I've used Dupont Imron with good success on exhausts. Eastwood has good line of exhaust-paints.
Oven heat just speeds up natural curing of 2-part catalysed paints. It will harden on its own over course of week or two anyway. You can also use hair-dryer/heat-gun to speed up this process as well. In general, the fastest a paint dries, the less durable and tough it tends to be. The strongest paints takes a couple weeks to cure and harden.
Heat curing the paint will help.
A recent "prototype" oven :wow No it didn't melt down, but I was concerned about it. :teeth
Surface preparation is key. Sand, wipe down with acetone, then wipe down with rubbing alcohol.