Lead free is available various places, sold mostly as racing gas, and for other unusual engines. I buy mine a Bayside Oil in Santa Cruz. It is VERY expensive, I think about $12 per gallon. It is unleaded, and I think it has 94 octane (although that might be measured different from on-road gasoline).
It is ILLEGAL to use on-road. Repeat, do not drive on a public road with this. By law, all gasoline used on-road in California has to be oxygenated, and ethanol is the most common way of doing that. Because of this, it is dyed, and theoretically can be detected in your tank if you are stopped (whether this ever
I go through a few gallons per month in chainsaws and similar power tools. The reason I buy it: (a) it doesn't age as fast as gasoline with ethanol (because ethanol is hygroscopic, and the water catalyzes the polymerization reaction that turns gasoline into varnish, which gums up small carburetors). (b) The various rubber components in small carburetors and in the fuel system live longer when not exposed to ethanol, MTBE, and other oxygenators.